MATERIAL SAFETY DATA SHEET MANGANESE CARBONATE According to Regulation (EC) No. 453/2010 SECTION 1: Identification Of The Substance / Mixture And Of The Company / Undertaking 1.1 Product Identification Product form Product ( Substance) Name Synonym Molecular Formula CAS Number EC number REACH Registration No.: : : : : : :Substance Manganese Carbonate Manganese(II) carbonate MnCO3 598-62-9 209-942-9 01-2119442695-32-0010 1.2 Relevant identified uses of the substance or mixture and uses advised against 1.2.1 Relevant identified uses Main Use Category Use of the Substance / Preparation: :Industrial Use Chemical Industry, To Manufacture Surface treatment Chemicals 1.2.2 Uses Advised Against No Additional Information Available 1.3 Details Of Manufacturer & 24/7 Contact No: Navadia Group Of Companies. Plot No 1308-09-03-04 GIDC Estate Ankleshwar 393002 Gujarat (India) Phones : +91-2646-252111 / 24 Hours Contact Number : +91-97272-70009 2.1 Classification of the substance or mixture SECTION 2: Hazards Identification The substance is not classified as hazardous to health or the environment according to the CLP regulation.Chemical Industry, To Manufacture Surface treatment Chemicals Not Classified No Information Available No Information Available: : : :Classification according to Regulation (EC) No 1272/2008 Classification according to Directive 67/548 / EEC or Directive 1999/45 /CE Specific information on hazards to humans and the environment Other hazards that do not result in classification 2.2 Label elements Labelling according to Regulation (EC) No 1272/2008 : Not applicable Hazard pictograms : Not applicable, Hazard statements : Not applicable, Signal word : Not applicable, 2.3 Other hazards This Substance / Mixture Does Not Meet the PBT Criteria of REACH, Annex XIII This Substance / Mixture Does Not Meet the vPvB Criteria of REACH, Annex XIII SECTION 3: Composition / Information on Ingredients 3.1 Substances Name Of Product (Main Constituent) __________________ Manganese Carbonate Product Identifier ____________________________________ CAS No : 598-62-9 EC Number : 209-942-9 REACH Reg. No. : 17-2120207594-58-0000 % _____ >80% Classification according to Directive 67/548/EEC ---------------------------------------------------------------------------- Regulation (EC) No. 1272/2008 (CLP) ________________________________________________ Not Classified -------------------- Not Classified 3.2 Mixtures Not Applicable
SECTION 4: First aid measures 4.1 Description of First Aid Measures General : When in doubt or if symptoms are observed, get medical advice. Never give anything by mouth to an unconscious person. Eye Contact : Rinse opened eye for several minutes under running water. Then consult doctor. Skin Contact : Wash with water and soap and rinse thoroughly. Inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. Keep the patient warm, If breathing is difficult, give oxygen. Get medical attention. Serious Inhalation : Data Not Available Ingestion: Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar, tie, belt or waistband. Serious Ingestion: Not available. 4.2 Most Important Symptoms and Effects, both acute and delayed4.3 Indication of any immediate medical attention and any special treatment needed . No Additional Information AvailableIn Case of doubt or persistent symptoms, consult always a physician. Section 5 - Fire and Explosion Data 5.1. Extinguishing Media5.2. Special Hazards arising from the substance or Mixture5.3. Advice for Fire Fighters Suitable extinguishing Media :Co-ordinate fire fighting measures to the fire surrounding Fire Hazard : May Release hazardous fumes Explosion Hazard : Not Explosive Reactivity : The product is stable at normal handling and storage conditions.Protection during fire fighting : In case of fire wear self contained breathing apparatus. Section 6 - Accidental Release Measures 6.1. Personal precautions, protective equipment and emergency procedures General Measures : Prevent unauthorised access. See protective measures under point 7 And 8Protective Equipment : Use Personal Protective equipment as required 6.1.1. For Non Emergency Personnel Protective Equipment : Use Personal Protective equipment as required 6.1.2. For Emergency Responders Avoid release to the environment. 6.2. Environmental Precautions6.3. Method and material for containment and cleaning up For Containment : Collect spillage Methods for cleaning up : Shovel into suitable and closed container for disposal. Clean contaminated objects and area thoroughly observing environmental regulations. Other Information : Treat the recovered material as prescribed in the section on waste disposal. 6.4. Reference to other sections Treat the recovered material as prescribed in the section on waste disposal. See protective measures under point 7 and 8
SECTION 7: Handling and Storage 7.1. Precautions for safe handling Precautions for safe handling : Provide adequate ventilation. Avoid generation of dust Hygiene Measures : Do not eat, drink or smoke when using this product. Wash contaminated cloths before reuse. Technical Measures : Minimize generation of dust. Keep container tightly closed and in a well-ventilated place Storage conditions : Store in original container Incompatible products : Acid. Oxidising. Metals. Storage area : Use only in well-ventilated areas 7.2. Conditions for Sale Storage, Including Incompatibilities.7.3. Specific end use(s) No additional information available SECTION 8: Exposure controls/personal protection 8.1. Control parameters Name Of Product / CAS No : Manganese carbonate / 598-62-9 PNEC (Water) PNEC aqua (freshwater) : 0.0084 mg/l PNEC aqua (marine water) : 0.00084 mg/l PNEC aqua (intermittent, freshwater) : 0.011 mg/l PNEC (Sediment) PNEC sediment (freshwater) : 8.18 mg/kg dwt PNEC sediment (marine water) : 0.82 mg/kg dwt PNEC (Soil) PNEC soil : 8.15 mg/kg dwt PNEC (STP) PNEC sewage treatment plant : 100 mg/l 8.2. Exposure controls Personal protective equipment : Gloves. Safety glasses Protective clothing Dust Mask Hand protection : Wear suitable gloves Eye protection : Dust protection eye glasses Skin and body protection : Wear suitable protective clothing and gloves. Respiratory protection : Dust/aerosol mask with filter type P3. If technical exhaust or ventilation measures are not possible or insufficient, respiratory protection must be worn SECTION 9: Physical and chemical properties Information on basic physical and chemical properties Physical State & Appearance : Ivory To Light Brown Colour Powder Odour : Odourless Odour threshold : Not Determined pH : Not Applicable Melting point : 447°C Freezing Point : No Data Available Boiling point : No Data Available Flash Point : No Data Available flammability (solid, gaseous) : Non Flammable Explosive Limit : Not Explosive Vapour Pressure : No Data Available Relative Vapour Density @ 20°C : No Data Available Relative Density : 3.27 Solubility:Water : 0.00363 g/l Self Ignition Temperature : Non Flammable Decomposition Temperature : 380°C Viscosity, Kinematic : No Data Available Viscosity, Dynamic : No Data Available Explosive Properties : Not Explosive Oxidising Properties : Not Oxidizing
SECTION 10: Stability and reactivity 10.1. Reactivity The Product is stable at normal handling and storage conditions. 10.2. Chemical Stability Stable Under Normal Conditions. 10.3. Possibility of hazardous reactions Refer to section 10.1 on Reactivity. 10.4. Conditions to avoid Avoid generation of dust. 10.5. Incompatible materials Acidic. Bases 10.6. Hazardous decomposition products Under fire conditions, hazardous fumes will be present. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity : Not classified Skin corrosion/irritation : Not classified Serious eye damage/irritation : Not classified Respiratory or skin sensitisation : Not classified Germ cell mutagenicity : Not classified Carcinogenicity : Not classified Reproductive toxicity : Not classified Specific target organ toxicity (single exposure) : Not classified Specific target organ toxicity (repeated exposure) : Not classified Aspiration hazard : Not classified SECTION 12: Ecological information 12.1 Toxicity Manganese carbonate (598-62-9) LC50 other aquatic organisms 1 : > 100 EC50 Daphnia 1 : > 100 NOEC (chronic) : 1.3 mg/l 12.2 Persistence and degradability No additional information availableNo additional information available 12.3 Bio accumulative potential No additional information available 12.4 Mobility in soil Manganese carbonate (598-62-9) This substance/mixture does not meet the PBT criteria of REACH, annex XIII. This substance/mixture does not meet the vPvB criteria of REACH, annex XIII 12.5 Results of PBT and vPvB assessment No additional information available 12.6 Other adverse effects
SECTION 13: Disposal considerations 13.1 Waste treatment methods Do not empty into drains, dispose of this material and its container at hazardous or special waste collection point. Dispose according to legislation. SECTION 14: Transport information Safety, health and environmental regulations/legislation specific for the substance or mixture No dangerous good in sense of transport regulations. According to : ADR, RID, ADN, IMDG, ICAO. UN Number : Not Regulated. UN proper shipping name : Not Regulated. Transport hazard class(es) : Not Regulated. Packing group : Not Applicable Environmental hazards : Not Applicable Special precautions for user : Not Applicable Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code : Not Applicable (Non-hazardous substance). SECTION 15: Regulatory information EU-Regulations : No REACH Annex XVII restrictions National regulations : No additional information available Chemical safety assessment : This substance is classified as not hazardous according to regulation (EC) 1272/2008 [CLP] SECTION 16: Other information Employers should use this information only as a supplement to other information gathered by them, and should make independent judgement of suitability of this information to ensure proper use and protect the health and safety of employees. This information is furnished without warranty, and any use of the product not in conformance with this Material Safety Data Sheet, or in combination with any other product or process, is the responsibility of the user. Department issuing SDS: Navadia Group Of Companies (Marketing Department) Abbreviations and acronyms: ADR : Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) GHS : Globally Harmonized System of Classification and Labelling of Chemicals EINCES : European Inventory of Existing Commercial Chemical Substances CAS : Chemical Abstracts Service (division of the American Chemical Society) VbF : Verordnung uber brennbare Flussigkeiten (Ordinance on the storage of combustible liquids, Austria) LC50 : Lethal concentration, 50 percent LD50 : Lethal dose, 50 percent vPvB : very Persistent and very Bioaccumulative ACGIH : American Conference of Governmental Industrial Hygienists (USA) OSHA : :Occupational Safety and Health Administration (USA) NTP : National Toxicology Program (USA) IARC : International Agency for Research on Cancer EPA : Environmental Protection Agency (USA) CLP The regulation on classification, labelling and packagingVersion : 1.2 References : Not Available Other Special Considerations : Not Available Created (DD/MM/YYYY) : Last Updated (DD/MM/YYYY) : Not Applicable
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